New FTIR CO2 high resolution spectra are recorded in argon and nitrogen matrices at 11 K at high dilution. Their evolution with CO2 diffusion at higher temperature is also traced. New observations are discussed in regard to previous works. Even at high dilution (1/10 000), the temperature increase causes appearance of several bands both in argon and nitrogen. Identification of carbon dioxide dimer absorptions is tentatively proposed.
An International Journal devoted to Applications of Infrared and Raman Spectroscopy
Vibrational Spectroscopy provides a vehicle for the publication of original research in vibrational spectroscopy. It covers infrared, near-infrared and Raman spectroscopies and publishes papers dealing with developments in applications, theory, techniques and instrumentation. The topics covered by the journal include: Sampling techniques - including diffuse ...
Vibrational Spectroscopy provides a vehicle for the publication of original research in vibrational spectroscopy. It covers infrared, near-infrared and Raman spectroscopies and publishes papers dealing with developments in applications, theory, techniques and instrumentation. The topics covered by the journal include: Sampling techniques - including diffuse reflectance spectroscopy, reflection-absorption spectroscopy, and photoacoustic spectroscopy; Vibrational spectroscopy coupled with separation techniques; Instrumentation (Fourier transform, conventional and laser based); Data manipulation; Expert systems for identification and structure elucidation; Spectra-structure correlation and group frequencies. The application areas covered include: Analytical chemistry; Bio-organic and bio-inorganic chemistry; Organic chemistry; Inorganic chemistry; Catalysis; Environmental science; Industrial chemistry; Materials science; Physical chemistry; Polymer science; Process control; Specialized problem solving. The journal provides its readership with a concise picture of the “state of the art” of vibrational spectroscopy on a regular basis. In order to achieve this goal the journal publishes review articles, news, and book reviews, as well as original research papers and short communications.
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