The rototranslational absorption spectrum of gaseous N2 is analyzed, considering quadrupolar and hexadecapolar induction mechanisms. The available experimental data are accounted for by using a line-shape analysis in which empirical profiles describe the single-line translational profiles. We thus derive the simple procedure that allows one to predict the N2 spectrum at any temperature. On the basis of the results obtained for the pure gas, we also propose a procedure to compute the far-infrared spectrum of the N2–Ar gaseous mixture. The good agreement between computed and experimental N2–Ar data indicates that it is possible to predict the far-infrared absorption induced by N2 on the isotropic polarizability of any interacting partner.
The rototranslational absorption spectrum of N2-H2 gaseous mixtures has been measured at five different temperatures from 298 to 90 K in the frequency range 80–850 cm-1. The absorption spectra due to N2-H2 interactions have been analyzed considering only the quadrupolar induction mechanism. With this assumption, the experimental data are fairly well accounted for, thereby providing a procedure for predicting the N2-H2 spectrum over a wide temperature range.
