Молекулярная спектроскопия Молекулярная спектроскопия
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Figure 2. Evolution of the OH anti-symmetric (ν3) and symmetric (Vi) stretching modes, and of the bending mode (ν2) of supercritical water at T=380°C as a function of pressure (density) in the range 25-180 bar (0.01-0.1 g.cm-3). (B) Infrared band intensities (Km.mol-1) associated with the OH stretching and bending modes of small cyclic water clusters as calculated by DFT methods (see text).



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