Молекулярная спектроскопия Молекулярная спектроскопия
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Figure 10. Unidentified  Q-branch  like  absorptions  in  the  observed (CO2)2+(CO2)3 spectrum. The features labeled QA and QB clearly do not belong to the dimer or cyclic trimer. Moreover, they are within 0.4 cm-1 of the predicted vibrational origin of the trimer asymmetric top isomer from model potentials. Overlap of (CO2)3 transitions with the head of both QA and QB is coincidental (conditions: 1.8% CO2 in He,P0=1 bar)

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