Молекулярная спектроскопия Молекулярная спектроскопия
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Figure 3. Rototranslational collision-induced spectra of N2-CH4 pairs. Markers denote experimental data by (Birnbaum et al. 1993) at temperatures of 162°K, 195°K, and 297°K. Solid thick lines show our theoretical results, based on fitted parameters m obtained in this work. Separate dipolar contributions are marked with thin lines and denote induction by: dots, N2  Θ, dash-dot-dot, N2 Φ; dashes, CH4 Ω; dash-dot, CH4 Φ; dot-dash-dash, CH4 Q6 ; and long dashes, double transitions.
G. Birnbaum, A. Borysow, A. Buechele, Collision‐induced absorption in mixtures of symmetrical linear and tetrahedral molecules: Methane–nitrogen, J. Chem. Phys. 99, 3234 (1993); https://doi.org/10.1063/1.465132



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