Table 3. Measured line positions, intensities and, air- and self-broadened line shape parameters for the strongest transitions in the ν3 band of H216O. Vibrational Rotational Position and Line % Width % T. dep. % Shift T. dep. Speed % quanta quantum unc.b intensity c unc. (b0L) unc. (n)e unc. (δ0)d and (δ′)f and dependence g unc. numbers a unc. unc. 5 ← 1 3 3 1 ← 4 3 2 3647.552909(5) 3.9068e−20 0.02 0.07986 0.06 0.6498 0.35 −0.003072(24) +0.041(5) 0.0932 2.3 0.45275 0.21 +0.03200(150) 5 ← 1 4 0 4 ← 5 0 5 3649.283053(3) 1.4542e−19 0.01 0.08778 0.02 0.6799 0.22 −0.008648(16) +0.239(4) 0.0948 1.2 0.54310 0.22 −0.03052(125) 5 ← 1 4 1 4 ← 5 1 5 3650.636109(5) 4.6465e−20 0.02 0.08425 0.06 0.6690 0.31 −0.008273(25) +0.259(5) 0.0889 1.9 0.53162 0.17 −0.03570(148) 5 ← 1 3 1 2 ← 4 1 3 3651.365171(5) 4.8515e−20 0.02 0.09201 0.05 0.7617 0.28 −0.003646(27) +0.082(6) 0.0817 2.1 0.52116 0.17 −0.01935(148) 5 ← 1 3 2 2 ← 4 2 3 3656.303543(4) 1.0066e−19 0.01 0.08863 0.03 0.6829 0.23 −0.003227(17) +0.007(4) 0.0971 1.3 0.51153 0.11 +0.02370(127) 5 ← 1 3 0 3 ← 4 0 4 3668.776579(5) 6.3754e−20 0.02 0.09463 0.05 0.7613 0.26 −0.008368(21) +0.205(5) 0.0888 2.0 0.55405 0.21 +0.01069(146) 5 ← 1 3 1 3 ← 4 1 4 3670.749725(3) 1.8199e−19 0.01 0.09188 0.02 0.7391 0.22 −0.006296(15) +0.152(4) 0.1138 0.9 0.52044 0.14 +0.00318(132) 5 ← 1 2 2 0 ← 3 2 1 3674.957865(4) 8.7249e−20 0.02 0.09319 0.04 0.7255 0.26 −0.003961(21) +0.008(5) 0.1139 1.0 0.50407 0.19 −0.00679(146) 5 ← 1 2 1 1 ← 3 1 2 3676.019555(3) 1.6951e−19 0.01 0.09712 0.03 0.7448 0.21 −0.001715(17) +0.027(4) 0.1418 0.5 0.47565 0.14 −0.02265(136) 5 ← 1 2 2 1 ← 3 2 2 3679.436265(7) 2.9231e−20 0.03 0.09212 0.09 0.7378 0.41 −0.002977(34) +0.013(8) 0.0940 2.9 0.51508 0.36 −0.02261(192) 5 ← 1 2 0 2 ← 3 0 3 3688.451403(3) 2.1638e−19 0.01 0.10028 0.02 0.7975 0.18 −0.007969(18) +0.271(4) 0.1304 0.7 0.52353 0.09 −0.03552(144) 5 ← 1 2 1 2 ← 3 1 3 3691.298176(5) 6.3327e−20 0.02 0.09666 0.05 0.7971 0.24 −0.005427(22) +0.154(5) 0.1138 1.4 0.53819 0.17. −0.00706(152) 5 ← 1 1 1 0 ← 2 1 1 3701.805704(5) 4.5122e−20 0.03 0.10310 0.09 0.7575 0.41 −0.001666(43) +0.024(9) 0.1341 1.6 0.48452 0.23 −0.00932(164) 5 ← 1 1 0 1 ← 2 0 2 3709.402295(4) 6.5867e−20 0.02 0.10408 0.05 0.8000 0.23 −0.008845(24) +0.262(5) 0.1122 1.4 0.47272 0.16 −0.01230(142) 5 ← 1 1 1 1 ← 2 1 2 3712.204495(3) 1.4215e−19 0.02 0.10122 0.03 0.8132 0.18 −0.003487(19) +0.108(4) 0.1175 0.9 0.57025 0.10 −0.00484(131) 5 ← 1 3 1 3 ← 3 1 2 3722.222317(6) 3.7466e−20 0.04 0.10125 0.07 0.8222 0.29 −0.003760(36) +0.062(8) 0.1033 2.0 0.53106 0.22 +0.01528(173) 5 ← 1 6 5 2 ← 6 5 1 3724.893608(12) 3.8903e−21 0.11 0.05395 0.24 0.5622 2.42 −0.006256(122) +0.243(23) 0.1137 0.0 0.25449 1.23 +0.01173(196) 5 ← 1 5 5 1 ← 5 5 0 3726.617094(5) 3.0717e−20 0.04 0.05146 0.06 0.6363 0.39 −0.006422(16) +0.201(4) 0.1163 1.1 0.27120 0.79 −0.00311(115) 5 ← 1 5 5 0 ← 5 5 1 3726.625450(16) 8.1400e−21 0.04 0.05146 h 0.06 0.6363 h 0.39 −0.006422(16)h +0.201(4)h 0.1163 h 1.1 0.27120 h 0.79 −0.00311(115)h 5 ← 1 0 0 0 ← 1 0 1 3732.134215(3) 1.2119e−19 0.02 0.10356 0.03 0.7609 0.20 −0.002449(19) −0.044(4) 0.1139 1.0 0.48528 0.10 +0.00813(118) 5 ← 1 4 2 3 ← 4 2 2 3734.272763(9) 1.5319e−20 0.04 0.09252 0.12 0.7816 0.55 −0.004549(61) +0.053(12) 0.0717 5.8 0.49273 0.39 +0.00905(258) 5 ← 1 6 4 2 ← 6 4 3 3734.644881(8) 1.3528e−20 0.04 0.07098 0.13 0.6565 0.72 −0.002608(53) +0.021(11) 0.1059 3.2 0.38267 0.47 +0.00780(223) 5 ← 1 5 4 2 ← 5 4 1 3734.930719(4) 3.5339e−20 0.02 0.06713 0.06 0.6146 0.33 −0.005943(20) +0.179(4) 0.1140 1.1 0.35805 0.21 +0.00733(97) 5 ← 1 5 4 1 ← 5 4 2 3735.444698(8) 1.1737e−20 0.06 0.06713 h 0.06 0.6146 h 0.33 −0.005943(20)h +0.179(4)h 0.1140 h 1.1 0.35805 h 0.21 +0.00733(97)h 5 ← 1 5 3 3 ← 5 3 2 3735.492633(4) 2.1855e−20 0.04 0.08273 0.10 0.7496 0.51 −0.007233(50) +0.225(10) 0.0853 3.8 0.45219 0.33 −0.02066(197) 5 ← 1 6 4 1 ← 4 4 0 3736.682610(4) 2.7242e−20 0.04 0.06436 0.03 0.6750 0.28 −0.005258(16) +0.117(3) 0.1004 1.2 0.33494 0.14 +0.00427(97) 5 ← 1 4 4 0 ← 4 4 1 3736.743180(3) 8.1827e−20 0.03 0.06436 h 0.03 0.6750 0.28 −0.005258(16)h +0.117(3)h 0.1004 h 1.2 0.33494 h 0.14 +0.00427(97)h 5 ← 1 2 1 2 ← 2 1 1 3738.400727(7) 2.3979e−20 0.03 0.10173 0.10 0.7905 0.38 −0.004931(44) +0.045(10) 0.1045 2.7 0.52339 0.29 +0.03742(204) 5 ← 1 4 3 2 ← 4 3 1 3741.306224(7) 2.0324e−20 0.03 0.08138 0.10 0.7156 0.46 −0.006339(40) +0.223(9) 0.1153 2.3 0.40428 0.37 −0.01145(193) 5 ← 1 4 3 1 ← 4 3 2 3743.946449(5) 5.6577e−20 0.03 0.08090 0.06 0.7061 0.31 −0.00266(22) +0.087(5) 0.1023 1.8 0.42272 0.19 +0.02788(138) 5 ← 1 3 2 2 ← 3 2 1 3744.509479(4) 1.0312e−19 0.03 0.09475 0.06 0.7350 0.30 −0.005570(34) +0.054(5) 0.1257 1.2 0.49111 0.13 +0.02622(152) 5 ← 1 3 3 1 ← 3 3 0 3744.651240(3) 1.6470e−19 0.04 0.07779 0.05 0.6947 0.32 −0.005122(25) +0.123(4) 0.1001 1.4 0.39568 0.11 +0.01098(136) 5 ← 1 3 3 0 ← 3 3 1 3745.086704(5) 5.4846e−20 0.03 0.07805 0.06 0.6951 0.32 −0.003487(21) +0.079(5) 0.0987 2.0 0.39294 0.20 +0.01731(138) 5 ← 1 1 1 1 ← 1 1 0 3749.329153(3) 1.6139e−19 0.03 0.10300 0.04 0.7293 0.22 −0.007617(18) +0.187(4) 0.1077 1.2 0.48272 0.10 +0.01396(128) 5 ← 1 2 2 1 ← 2 2 0 3749.573789(4) 7.3092e−20 0.03 0.09188 0.05 0.7274 0.29 −0.004615(22) +0.038(5) 0.1004 1.9 0.50058 0.15 −0.005102(141) 5 ← 1 2 2 0 ← 2 2 1 3752.212617(3) 2.1784e−19 0.03 0.09207 0.03 0.7123 0.22 0.003649(17) +0.103(4) 0.1186 1.0 0.49482 0.09 −0.06115(125) 5 ← 1 3 2 1 ← 3 2 2 3756.616451(6) 3.3386e−20 0.03 0.09238 0.06 0.7208 0.35 −0.002451(32) +0.123(7) 0.0705 3.7 0.48502 0.26 −0.06420(174) 5 ← 1 1 1 0 ← 1 1 1 3759.844496(5) 5.3490e−20 0.03 0.10269 0.05 0.7339 0.27 +0.001493(27) −0.026(6) 0.0938 1.9 0.51971 0.18 −0.02833(154) 5 ← 1 4 2 2 ← 4 2 3 3765.760277(5) 4.4535e−20 0.03 0.09386 0.05 0.7320 0.30 −0.002623(28) +0.098(6) 0.1016 1.8 0.52170 0.20 −0.03272(157) 5 ← 1 2 1 1 ← 2 1 2 3769.888988(5) 7.1630e−20 0.03 0.10181 0.05 0.7421 0.24 −0.0010439(24) +0.039(5) 0.1050 1.5 0.54520 0.15 −0.03661(147) 5 ← 1 1 0 1 ← 0 0 0 3779.493135(7) 4.2344e−20 0.03 0.10396 0.07 0.7778 0.28 −0.005051(37) +0.202(8) 0.1081 1.9 0.48063 0.27 −0.00530(208) 5 ← 1 5 2 3 ← 5 2 4 3779.762272(19) 6.3317e−21 0.11 0.09269 0.28 0.7799 1.26 −0.004260(142) +0.194(29) 0.1206 5.9 0.50954 0.80 −0.03944(519) 5 ← 1 3 1 2 ← 3 1 3 3784.583804(12) 1.2400e−20 0.05 0.09944 0.14 0.7683 0.69 −0.002995(60) +0.100(F) 0.0780 6.6 0.52665 0.48 −0.03098(323) 5 ← 1 2 1 2 ← 1 1 1 3796.439552(5) 5.1640e−20 0.02 0.10079 0.06 0.7963 0.25 −0.002924(25) +0.044(6) 0.1124 1.5 0.57438 0.17 −0.01152(155) 5 ← 1 2 0 2 ← 1 0 1 3801.418689(3) 2.169e−19 0.01 0.10244 0.02 0.7800 0.17 +0.001839(17) −0.110(4) 0.1290 0.7 0.45943 0.08 +0.01591(130) 5 ← 1 2 1 1 ← 1 1 0 3807.013666(3) 1.4881e−19 0.01 0.10196 0.03 0.7566 0.19 −0.005061(17) +0.113(4) 0.1332 0.7 0.47217 0.10 +0.00423(128) 5 ← 1 3 1 3 ← 2 1 2 3816.091708(3) 2.1334e−19 0.04 0.09660 0.03 0.8228 0.17 −0.002809(16) +0.077(4) 0.1094 0.9 0.53275 0.09 +0.00213(126) 5 ← 1 3 0 3 ← 2 0 2 3820.738533(4) 8.1246e−20 0.03 0.09906 0.04 0.8209 0.19 +0.006586(21) −0.118(4) 0.1206 0.9 0.52530 0.13 +0.03247(131) 5 ← 1 3 2 2 ← 2 2 1 3821.764198(4) 9.6616e−20 0.03 0.09244 0.03 0.7768 0.21 −0.004816(18) +0.178(4) 0.1016 1.0 0.53609 0.12 +0.00487(126) 5 ← 1 3 2 1 ← 2 2 0 3826.753905(6) 3.2301e−20 0.03 0.09265 0.06 0.7940 0.31 −0.002937(31) +0.149(7) 0.0983 2.2 0.51427 0.25 +0.00294(172) 5 ← 1 3 1 2 ← 2 1 1 3831.686304(3) 6.4733e−20 0.02 0.09808 0.05 0.7903 0.23 −0.007410(21) +0.212(4) 0.1426 0.9 0.47214 0.15 −0.00028(134) 5 ← 1 4 1 4 ← 3 1 3 3834.983083(4) 6.9062e−20 0.02 0.09085 0.04 0.7815 0.23 −0.003089(19) +0.087(4) 0.1014 1.4 0.51778 0.14 −0.01483(127) 5 ← 1 4 0 4 ← 3 0 3 3837.869274(3) 2.2627e−19 0.02 0.09449 0.02 0.8051 0.17 +0.002226(16) −0.030(4) 0.1123 0.9 0.55835 0.08 −0.00332(121) 5 ← 1 4 3 1 ← 3 3 0 3841.044816(5) 4.3007e−20 0.02 0.08056 0.05 0.7525 0.29 −0.005008(23) +0.106(5) 0.0949 1.9 0.45808 0.21 −0.005428(138) 5 ← 1 4 2 3 ← 3 2 2 3843.750878(5) 3.8461e−20 0.02 0.08774 0.06 0.7490 0.31 −0.006599(27) +0.250(6) 0.0808 2.7 0.48491 0.22 −0.04377(151) 5 ← 1 5 1 5 ← 4 1 4 3852.057460(3) 1.799e−19 0.02 0.08285 0.02 0.6641 0.21 −0.002941(14) +0.048(3) 0.1025 0.9 0.50371 0.10 +0.03225(113) 5 ← 1 4 2 2 ← 3 2 1 3853.966209(4) 1.1795e−19 0.02 0.09060 0.06 0.7259 0.25 −0.004828(27) +0.113(4) 0.1093 1.2 0.45531 0.13 −0.01779(136) 5 ← 1 4 1 3 ← 3 1 2 3854.438182(3) 1.7698e−19 0.02 0.09371 0.03 0.7600 0.20 −0.006200(18) +0.180(3) 0.1132 0.8 0.48978 0.10 +0.00503(125) 5 ← 1 5 3 3 ← 4 3 2 3861.787793(5) 4.3852e−20 0.02 0.07651 0.05 0.6398 0.3 −0.006813(21) +0.224(5) 0.0903 2.0 0.41061 0.22 3 −0.01382(130) 5 ← 1 5 2 4 ← 4 2 3 3865.111525(4) 8.7287e−20 0.01 0.08366 0.04 0.6489 0.25 −0.005867(16) +0.176(4) 0.0804 1.8 0.48558 0.14 −0.00470(115) 5 ← 1 6 1 6 ← 5 1 5 3869.192640(5) 4.3259e−20 0.02 0.07212 0.06 0.5633 0.40 −0.003755(20) +0.138(5) 0.0989 1.8 0.44219 0.27 −0.03725(139) 5 ← 1 6 0 6 ← 5 0 5 3870.129400(3) 1.3071e−19 0.02 0.07502 0.03 0.5687 0.28 −0.002437(14) +0.066(3) 0.1122 1.0 0.46601 0.14 −0.02159(118) 5 ← 1 5 1 4 ← 4 1 3 3874.402204(5) 4.3610e−20 0.02 0.08965 0.06 0.7571 0.29 −0.003841(25) +0.048(6) 0.1067 1.7 0.48423 0.26 +0.02435(149) 5 ← 1 5 2 3 ← 4 2 2 3880.191418(6) 3.2252e−20 0.04 0.09002 0.09 0.7992 0.34 −0.008579(37) +0.274(7) 0.0841 1.5 0.42255 0.35 −0.04145(172) 5 ← 1 6 2 5 ← 5 2 4 3880.354707(8) 2.0277e−20 0.04 0.07755 0.10 0.6602 0.56 −0.006581(41) +0.220(9) 0.0831 4.0 0.44962 0.43 −0.02845(209) 5 ← 1 7 1 7 ← 6 1 6 3885.659922(4) 8.2167e−20 0.02 0.06053 0.03 0.4314 0.49 −0.005205(16) +0.245(3) 0.1244 1.0 0.41281 0.25 +0.00543(152) 5 ← 1 7 0 7 ← 6 0 6 3886.077259(6) 2.7546e−20 0.03 0.06122 0.08 0.4374 0.66 −0.004804(23) +0.188(5) 0.1118 1.9 0.40657 0.38 −0.00560(156) 5 ← 1 6 1 5 ← 5 1 4 3891.299500(4) 8.2439e−20 0.02 0.08422 0.04 0.7240 0.26 −0.001818(18) +0.080(4) 0.0825 1.8 0.48291 0.21 +0.01712(130) 5 ← 1 7 2 6 ← 6 2 5 3899.441416(5) 4.3166e−20 0.02 0.06846 0.06 0.5620 0.46 −0.007623(20) +0.309(5) 0.1016 1.8 0.39714 0.33 −0.02657(140) 5 ← 1 8 1 8 ← 7 1 7 3901.666439(7) 1.5536e−20 0.04 0.04872 0.12 0.3387 1.36 −0.007656(29) +0.323(6) 0.1238 2.4 0.33904 0.63 −0.00579(203) 5 ← 1 8 0 8 ← 7 0 7 3701.846942(4) 4.7063e−20 0.02 0.04916 0.06 0.3487 0.80 −0.006893(14) +0.300(3) 0.1414 1.0 0.35210 0.34 +0.00249(125) 5 ← 1 6 2 4 ← 5 2 3 3904.188663(5) 6.2507e−20 0.02 0.08980 0.04 0.8442 0.26 −0.010112(24) +0.282(5) 0.0686 2.4 0.44701 0.26 −0.01733(143) 5 ← 1 7 3 5 ← 6 3 4 3904.294965(8) 2.0004e−20 0.04 0.07091 0.08 0.6833 0.64 −0.010097(44) +0.336(9) 0.0686 2.4 0.38176 0.54 −0.05943(210) 5 ← 1 8 2 7 ← 7 2 6 3916.328740(12) 7.6223e−21 0.07 0.05850 0.19 0.4763 1.53 −0.007960(69) +0.304(14) 0.1180 3.7 0.34959 0.78 +0.02588(327) 5 ← 1 9 1 9 ← 8 1 8 3917.285843(6) 2.3916e−20 0.05 0.03845 0.10 0.2782 1.40 −0.009660(20) +0.382(4) 0.1449 1.3 0.31084 0.47 −0.00976(161) 5 ← 1 9 0 9 ← 8 0 8 3917.362738(10) 8.0222e−21 0.08 0.03832 0.21 0.2462 2.96 −0.009508(41) +0.386(9) 0.1589 2.3 0.32391 0.79 −0.02155(270) 5 ← 1 8 1 7 ← 7 1 6 3920.088775(7) 2.3845e−20 0.04 0.06613 0.08 0.5513 0.62 −0.002285(33) −0.014(7) 0.1174 1.7 0.41709 0.38 +0.01892(185) 5 ← 1 7 3 4 ← 6 3 3 3925.134338(16) 6.7952e−21 0.11 0.09275 0.44 0.8176 1.30 −0.01874(30) +0.670(34) 0.1517 1.3 0.47332 0.71 −0.03337(210) 5 ← 1 7 2 5 ← 6 2 4 3925.175901(11) 1.0943e−20 0.09 0.09405 0.32 0.8745 0.77 −0.007859(27) +0.304(22) 0.1517 h 1.3 0.48481 0.52 −0.03337(210)h 5 ← 1 8 2 6 ← 7 2 5 3942.652393(9) 1.5313e−20 0.05 0.08167 0.12 0.8376 0.59 −0.008492(67) +0.314(13) 0.0984 3.1 0.47480 0.48 +0.03883(254) 5 ← 1 9 3 7 ← 8 3 6 3942.887054(15) 5.2038e−21 0.08 0.06023 0.27 0.5601 1.92 −0.01232(106) +0.427(21) 0.1507 3.1 0.36116 1.02 −0.01910(393) 5 ← 1 10 1 9 ← 9 1 8 3948.177129(9) 4.5535e−21 0.06 0.04092 0.24 0.2874 3.9 −0.006896(74) +0.273(13) 0.1689 2.2 0.31593 0.98 −0.005(F) 5 ← 1 8 3 5 ← 7 3 4 3949.983713(12) 1.0530e−20 0.05 0.08896 0.16 0.9354 0.69 −0.012090(98) +0.491(19) 0.1167 3.1 0.47575 0.57 −0.03868(317) The uncertainties listed under the various columns correspond to one sigma internal statistical uncertainty obtained from the least-squares fits. In the two row format, the numbers in the top row in each cell correspond to air-broadening of H2O, and the bottom numbers correspond to self-broadening of H2O. For all transitions, the temperature dependences of self-broadened half-width coefficients (n2) and self-shift coefficients (δ′) were fixed to 0.75 and 0.0, respectively. a For the first column, HITRAN [1], [2] vibrational codes V′ ← V″; for the second column J′ Ka′ Kc′ ← J″ Ka″ Kc″. b Positions and uncertainties in cm−1. c Line intensities (S) in cm/molecule at 296 K. d Lorentz half-width coefficients (and pressure-shift coefficients (δ0) in cm−1 atm−1 at 296 K. Pressure-shift uncertainties are given in parentheses in units of the last digit quoted. e The temperature dependence exponents of broadening coefficients have no units. No temperature dependences of self-broadening or self-shift coefficients were measured. f Temperature dependences of pressure shift coefficients, (H2O-air) in units of 10−4 cm−1 atm−1 K−1. Uncertainties are given in parentheses in units of the last digit quoted. g Speed dependence parameter has no units. The speed dependence parameters for both air- and self-broadening are assumed to be the same and hence only one value for each transition is determined. h Value were constrained to be identical to that of the transition listed just above it in this table; for example see 5 5 1 ← 5 5 0 and 5 5 0 ← 5 5 1 (see the text for further details).