The infrared O–D stretching spectrum of fully deuterated jet-cooled water clusters is reported. Sequential red-shifts in the single donor O–D stretches, which characterize the cooperative effects in the hydrogen bond network, were accurately measured for clusters up to (D2O)8. Detailed comparisons with corresponding data obtained for (H2O)n clusters are presented. Additionally, rotational analyses of two D2O dimer bands are presented. These measurements were made possible by the advent of infrared cavity ringdown laser absorption spectroscopy (IR-CRLAS) using Raman-shifted pulsed dye lasers, which creates many new opportunities for gas phase IR spectroscopy.
The purpose of The Journal of Chemical Physics is to bridge a gap between journals of physics and journals of chemistry by publishing quantitative research based on physical principles and techniques, as applied to "chemical" systems. Just as the fields of chemistry and physics have expanded, so have chemical physics subject areas, which include polymers, materials, surfaces/interfaces, and biological macromolecules, along with the traditional small molecule and condensed phase systems. The Journal of Chemical Physics (JCP) is published four times per month (48 issues per year) by the American Institute of Physics.
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